In quantum mechanics, the state of a spin-1/2 particle is often represented in the basis of the z z z -component of spin, S z S_z S z . However, we frequently need to find the eigenstates of the spin operator along an arbitrary direction n ^ \hat{n} n ^ .
Problem Statement# Our goal is to derive an expression for the state ∣ n ; + ⟩ |n; +\rangle ∣ n ; + ⟩ satisfying:
S ⃗ ⋅ n ⃗ ∣ n ; + ⟩ = + ℏ 2 ∣ n ; + ⟩ \vec{S} \cdot \vec{n} |n; +\rangle = +\frac{\hbar}{2} |n; +\rangle S ⋅ n ∣ n ; + ⟩ = + 2 ℏ ∣ n ; + ⟩
where n ^ \hat{n} n ^ is a unit vector defined by the spherical coordinates ( θ , ϕ ) (\theta, \phi) ( θ , ϕ ) :
n ⃗ = [ n x n y n z ] = [ sin θ cos ϕ sin θ sin ϕ cos θ ] \vec{n} = \begin{bmatrix} n_x \\ n_y \\ n_z \end{bmatrix} = \begin{bmatrix} \sin\theta \cos\phi \\ \sin\theta \sin\phi \\ \cos\theta \end{bmatrix} n = n x n y n z = sin θ cos ϕ sin θ sin ϕ cos θ
We work in the basis of S z S_z S z , where the basis states are:
∣ z ; + ⟩ = [ 1 0 ] , ∣ z ; − ⟩ = [ 0 1 ] |z; +\rangle = \begin{bmatrix} 1 \\ 0 \end{bmatrix}, \quad |z; -\rangle = \begin{bmatrix} 0 \\ 1 \end{bmatrix} ∣ z ; + ⟩ = [ 1 0 ] , ∣ z ; − ⟩ = [ 0 1 ]
The Spin Operator in Direction n ^ \hat{n} n ^ # The spin operator vector is S ⃗ = ℏ 2 σ ⃗ \vec{S} = \frac{\hbar}{2} \vec{\sigma} S = 2 ℏ σ , where σ ⃗ \vec{\sigma} σ are the Pauli matrices:
σ x = [ 0 1 1 0 ] , σ y = [ 0 − i i 0 ] , σ z = [ 1 0 0 − 1 ] \sigma_x = \begin{bmatrix} 0 & 1 \\ 1 & 0 \end{bmatrix}, \quad \sigma_y = \begin{bmatrix} 0 & -i \\ i & 0 \end{bmatrix}, \quad \sigma_z = \begin{bmatrix} 1 & 0 \\ 0 & -1 \end{bmatrix} σ x = [ 0 1 1 0 ] , σ y = [ 0 i − i 0 ] , σ z = [ 1 0 0 − 1 ]
The projection of the spin along n ^ \hat{n} n ^ is:
S ⃗ ⋅ n ⃗ = ℏ 2 ( n x σ x + n y σ y + n z σ z ) \vec{S} \cdot \vec{n} = \frac{\hbar}{2} (n_x \sigma_x + n_y \sigma_y + n_z \sigma_z) S ⋅ n = 2 ℏ ( n x σ x + n y σ y + n z σ z )
S ⃗ ⋅ n ⃗ = ℏ 2 [ n z n x − i n y n x + i n y − n z ] \vec{S} \cdot \vec{n} = \frac{\hbar}{2} \begin{bmatrix} n_z & n_x - i n_y \\ n_x + i n_y & -n_z \end{bmatrix} S ⋅ n = 2 ℏ [ n z n x + i n y n x − i n y − n z ]
Plugging in the spherical coordinates:
S ⃗ ⋅ n ⃗ = ℏ 2 [ cos θ sin θ ( cos ϕ − i sin ϕ ) sin θ ( cos ϕ + i sin ϕ ) − cos θ ] \vec{S} \cdot \vec{n} = \frac{\hbar}{2} \begin{bmatrix} \cos\theta & \sin\theta (\cos\phi - i\sin\phi) \\ \sin\theta (\cos\phi + i\sin\phi) & -\cos\theta \end{bmatrix} S ⋅ n = 2 ℏ [ cos θ sin θ ( cos ϕ + i sin ϕ ) sin θ ( cos ϕ − i sin ϕ ) − cos θ ]
S ⃗ ⋅ n ⃗ = ℏ 2 [ cos θ sin θ e − i ϕ sin θ e i ϕ − cos θ ] \vec{S} \cdot \vec{n} = \frac{\hbar}{2} \begin{bmatrix} \cos\theta & \sin\theta e^{-i\phi} \\ \sin\theta e^{i\phi} & -\cos\theta \end{bmatrix} S ⋅ n = 2 ℏ [ cos θ sin θ e i ϕ sin θ e − i ϕ − cos θ ]
Solving for the Eigenstate# We want to find ∣ n ; + ⟩ = [ c 1 c 2 ] |n; +\rangle = \begin{bmatrix} c_1 \\ c_2 \end{bmatrix} ∣ n ; + ⟩ = [ c 1 c 2 ] such that:
ℏ 2 [ cos θ sin θ e − i ϕ sin θ e i ϕ − cos θ ] [ c 1 c 2 ] = ℏ 2 [ c 1 c 2 ] \frac{\hbar}{2} \begin{bmatrix} \cos\theta & \sin\theta e^{-i\phi} \\ \sin\theta e^{i\phi} & -\cos\theta \end{bmatrix} \begin{bmatrix} c_1 \\ c_2 \end{bmatrix} = \frac{\hbar}{2} \begin{bmatrix} c_1 \\ c_2 \end{bmatrix} 2 ℏ [ cos θ sin θ e i ϕ sin θ e − i ϕ − cos θ ] [ c 1 c 2 ] = 2 ℏ [ c 1 c 2 ]
This leads to the eigenvalue equation:
[ cos θ − 1 sin θ e − i ϕ sin θ e i ϕ − cos θ − 1 ] [ c 1 c 2 ] = 0 \begin{bmatrix} \cos\theta - 1 & \sin\theta e^{-i\phi} \\ \sin\theta e^{i\phi} & -\cos\theta - 1 \end{bmatrix} \begin{bmatrix} c_1 \\ c_2 \end{bmatrix} = 0 [ cos θ − 1 sin θ e i ϕ sin θ e − i ϕ − cos θ − 1 ] [ c 1 c 2 ] = 0
From the first row:
c 1 ( cos θ − 1 ) + c 2 sin θ e − i ϕ = 0 c_1 (\cos\theta - 1) + c_2 \sin\theta e^{-i\phi} = 0 c 1 ( cos θ − 1 ) + c 2 sin θ e − i ϕ = 0
c 2 = 1 − cos θ sin θ e i ϕ c 1 c_2 = \frac{1 - \cos\theta}{\sin\theta} e^{i\phi} c_1 c 2 = s i n θ 1 − c o s θ e i ϕ c 1
Using trigonometric identities:
1 − cos θ = 2 sin 2 ( θ / 2 ) 1 - \cos\theta = 2 \sin^2(\theta/2) 1 − cos θ = 2 sin 2 ( θ /2 )
sin θ = 2 sin ( θ / 2 ) cos ( θ / 2 ) \sin\theta = 2 \sin(\theta/2) \cos(\theta/2) sin θ = 2 sin ( θ /2 ) cos ( θ /2 )
Thus:
c 2 = 2 sin 2 ( θ / 2 ) 2 sin ( θ / 2 ) cos ( θ / 2 ) e i ϕ c 1 = tan ( θ / 2 ) e i ϕ c 1 c_2 = \frac{2 \sin^2(\theta/2)}{2 \sin(\theta/2) \cos(\theta/2)} e^{i\phi} c_1 = \tan(\theta/2) e^{i\phi} c_1 c 2 = 2 s i n ( θ /2 ) c o s ( θ /2 ) 2 s i n 2 ( θ /2 ) e i ϕ c 1 = tan ( θ /2 ) e i ϕ c 1
The state is then:
∣ n ; + ⟩ = c 1 [ 1 tan ( θ / 2 ) e i ϕ ] |n; +\rangle = c_1 \begin{bmatrix} 1 \\ \tan(\theta/2) e^{i\phi} \end{bmatrix} ∣ n ; + ⟩ = c 1 [ 1 tan ( θ /2 ) e i ϕ ]
Normalization# To normalize the state:
⟨ n ; + ∣ n ; + ⟩ = ∣ c 1 ∣ 2 ( 1 + tan 2 ( θ / 2 ) ) = ∣ c 1 ∣ 2 sec 2 ( θ / 2 ) = 1 \langle n; + | n; + \rangle = |c_1|^2 (1 + \tan^2(\theta/2)) = |c_1|^2 \sec^2(\theta/2) = 1 ⟨ n ; + ∣ n ; + ⟩ = ∣ c 1 ∣ 2 ( 1 + tan 2 ( θ /2 )) = ∣ c 1 ∣ 2 sec 2 ( θ /2 ) = 1
∣ c 1 ∣ 2 = cos 2 ( θ / 2 ) |c_1|^2 = \cos^2(\theta/2) ∣ c 1 ∣ 2 = cos 2 ( θ /2 )
Choosing c 1 c_1 c 1 to be real and positive:
c 1 = cos ( θ / 2 ) c_1 = \cos(\theta/2) c 1 = cos ( θ /2 )
c 2 = cos ( θ / 2 ) tan ( θ / 2 ) e i ϕ = sin ( θ / 2 ) e i ϕ c_2 = \cos(\theta/2) \tan(\theta/2) e^{i\phi} = \sin(\theta/2) e^{i\phi} c 2 = cos ( θ /2 ) tan ( θ /2 ) e i ϕ = sin ( θ /2 ) e i ϕ
Final Result# The normalized eigenstate ∣ n ; + ⟩ |n; +\rangle ∣ n ; + ⟩ in the S z S_z S z basis is:
∣ n ; + ⟩ = [ cos ( θ / 2 ) sin ( θ / 2 ) e i ϕ ] |n; +\rangle = \begin{bmatrix} \cos(\theta/2) \\ \sin(\theta/2) e^{i\phi} \end{bmatrix} ∣ n ; + ⟩ = [ cos ( θ /2 ) sin ( θ /2 ) e i ϕ ]
This represents a general qubit state on the Bloch sphere.