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Spin Eigenstates in a General Direction

In quantum mechanics, the state of a spin-1/2 particle is often represented in the basis of the zz-component of spin, SzS_z. However, we frequently need to find the eigenstates of the spin operator along an arbitrary direction n^\hat{n}.

Problem Statement#

Our goal is to derive an expression for the state n;+|n; +\rangle satisfying: Snn;+=+2n;+\vec{S} \cdot \vec{n} |n; +\rangle = +\frac{\hbar}{2} |n; +\rangle

where n^\hat{n} is a unit vector defined by the spherical coordinates (θ,ϕ)(\theta, \phi): n=[nxnynz]=[sinθcosϕsinθsinϕcosθ]\vec{n} = \begin{bmatrix} n_x \\ n_y \\ n_z \end{bmatrix} = \begin{bmatrix} \sin\theta \cos\phi \\ \sin\theta \sin\phi \\ \cos\theta \end{bmatrix}

We work in the basis of SzS_z, where the basis states are: z;+=[10],z;=[01]|z; +\rangle = \begin{bmatrix} 1 \\ 0 \end{bmatrix}, \quad |z; -\rangle = \begin{bmatrix} 0 \\ 1 \end{bmatrix}

The Spin Operator in Direction n^\hat{n}#

The spin operator vector is S=2σ\vec{S} = \frac{\hbar}{2} \vec{\sigma}, where σ\vec{\sigma} are the Pauli matrices: σx=[0110],σy=[0ii0],σz=[1001]\sigma_x = \begin{bmatrix} 0 & 1 \\ 1 & 0 \end{bmatrix}, \quad \sigma_y = \begin{bmatrix} 0 & -i \\ i & 0 \end{bmatrix}, \quad \sigma_z = \begin{bmatrix} 1 & 0 \\ 0 & -1 \end{bmatrix}

The projection of the spin along n^\hat{n} is: Sn=2(nxσx+nyσy+nzσz)\vec{S} \cdot \vec{n} = \frac{\hbar}{2} (n_x \sigma_x + n_y \sigma_y + n_z \sigma_z) Sn=2[nznxinynx+inynz]\vec{S} \cdot \vec{n} = \frac{\hbar}{2} \begin{bmatrix} n_z & n_x - i n_y \\ n_x + i n_y & -n_z \end{bmatrix}

Plugging in the spherical coordinates: Sn=2[cosθsinθ(cosϕisinϕ)sinθ(cosϕ+isinϕ)cosθ]\vec{S} \cdot \vec{n} = \frac{\hbar}{2} \begin{bmatrix} \cos\theta & \sin\theta (\cos\phi - i\sin\phi) \\ \sin\theta (\cos\phi + i\sin\phi) & -\cos\theta \end{bmatrix} Sn=2[cosθsinθeiϕsinθeiϕcosθ]\vec{S} \cdot \vec{n} = \frac{\hbar}{2} \begin{bmatrix} \cos\theta & \sin\theta e^{-i\phi} \\ \sin\theta e^{i\phi} & -\cos\theta \end{bmatrix}

Solving for the Eigenstate#

We want to find n;+=[c1c2]|n; +\rangle = \begin{bmatrix} c_1 \\ c_2 \end{bmatrix} such that: 2[cosθsinθeiϕsinθeiϕcosθ][c1c2]=2[c1c2]\frac{\hbar}{2} \begin{bmatrix} \cos\theta & \sin\theta e^{-i\phi} \\ \sin\theta e^{i\phi} & -\cos\theta \end{bmatrix} \begin{bmatrix} c_1 \\ c_2 \end{bmatrix} = \frac{\hbar}{2} \begin{bmatrix} c_1 \\ c_2 \end{bmatrix}

This leads to the eigenvalue equation: [cosθ1sinθeiϕsinθeiϕcosθ1][c1c2]=0\begin{bmatrix} \cos\theta - 1 & \sin\theta e^{-i\phi} \\ \sin\theta e^{i\phi} & -\cos\theta - 1 \end{bmatrix} \begin{bmatrix} c_1 \\ c_2 \end{bmatrix} = 0

From the first row: c1(cosθ1)+c2sinθeiϕ=0c_1 (\cos\theta - 1) + c_2 \sin\theta e^{-i\phi} = 0 c2=1cosθsinθeiϕc1c_2 = \frac{1 - \cos\theta}{\sin\theta} e^{i\phi} c_1

Using trigonometric identities: 1cosθ=2sin2(θ/2)1 - \cos\theta = 2 \sin^2(\theta/2) sinθ=2sin(θ/2)cos(θ/2)\sin\theta = 2 \sin(\theta/2) \cos(\theta/2)

Thus: c2=2sin2(θ/2)2sin(θ/2)cos(θ/2)eiϕc1=tan(θ/2)eiϕc1c_2 = \frac{2 \sin^2(\theta/2)}{2 \sin(\theta/2) \cos(\theta/2)} e^{i\phi} c_1 = \tan(\theta/2) e^{i\phi} c_1

The state is then: n;+=c1[1tan(θ/2)eiϕ]|n; +\rangle = c_1 \begin{bmatrix} 1 \\ \tan(\theta/2) e^{i\phi} \end{bmatrix}

Normalization#

To normalize the state: n;+n;+=c12(1+tan2(θ/2))=c12sec2(θ/2)=1\langle n; + | n; + \rangle = |c_1|^2 (1 + \tan^2(\theta/2)) = |c_1|^2 \sec^2(\theta/2) = 1 c12=cos2(θ/2)|c_1|^2 = \cos^2(\theta/2)

Choosing c1c_1 to be real and positive: c1=cos(θ/2)c_1 = \cos(\theta/2) c2=cos(θ/2)tan(θ/2)eiϕ=sin(θ/2)eiϕc_2 = \cos(\theta/2) \tan(\theta/2) e^{i\phi} = \sin(\theta/2) e^{i\phi}

Final Result#

The normalized eigenstate n;+|n; +\rangle in the SzS_z basis is: n;+=[cos(θ/2)sin(θ/2)eiϕ]|n; +\rangle = \begin{bmatrix} \cos(\theta/2) \\ \sin(\theta/2) e^{i\phi} \end{bmatrix}

This represents a general qubit state on the Bloch sphere.

Spin Eigenstates in a General Direction
https://rohankulkarni.me/posts/notes/spin-eigenstates-general/
Author
Rohan Kulkarni
Published at
2022-09-26
License
CC BY-NC-SA 4.0